ISOMERISM :-
Isomerism is the phenomenon in which more than one compounds have the same chemical formula but different chemical structures. Chemical compounds that have identical chemical formulae but differ in properties and the arrangement of atoms in the molecule are called isomers. Therefore, the compounds that exhibit isomerism are known as isomers.
The word “isomer” is derived from the Greek words “isos” and “meros”, which mean “equal parts”. This term was coined by the Swedish chemist Jacob Berzelius in the year 1830.
Types
There are two primary types of isomerism, which can be further categorized into different subtype.
These primary types are Structural Isomerism and Stereoisomerism. The classification of different types of isomers is illustrated below.
Structural Isomerism
Structural isomerism is commonly referred to as constitutional isomerism. The functional groups and the atoms in the molecules of these isomers are linked in different ways. Different structural isomers are assigned different IUPAC names since they may or may not contain the same functional group. The different types of structural isomerism are discussed in this subsection.
Chain Isomerism
- It is also known as skeletal isomerism.
- The components of these isomers display differently branched structures.
- Commonly, chain isomers differ in the branching of carbon
- An example of chain isomerism can be observed in the compound C5H12, as illustrated below.
- The positions of the functional groups or substituent atoms are different in position isomers.
- Typically, this isomerism involves the attachment of the functional groups to different carbon atoms in the carbon chain.
- An example of this type of isomerism can be observed in the compounds having the formula C3H7Cl.
- It is also known as functional group isomerism.
- As the name suggests, it refers to the compounds that have the same chemical formula but different functional groups attached to them.
- An example of functional isomerism can be observed in the compound C3H6O.
- It is a rare type of isomerism and is generally limited to molecules that contain a divalent atom (such as sulfur or oxygen), surrounded by alkyl groups.
- Example: C4H10O can be represented as ethoxyethane (C2H5OC2H5) and methoxy-propane (CH3OC3H7).
- A tautomer of a compound refers to the isomer of the compound which only differs in the position of protons and electrons.
- Typically, the tautomers of a compound exist together in equilibrium and easily interchange.
- It occurs via an intramolecular proton transfer.
- An important example of this phenomenon is Keto-enol tautomerism.
- In ring-chain isomerism, one of the isomers has an open-chain structure whereas the other has a ring structure.
- They generally contain a different number of pi bonds.
- A great example of this type of isomerism can be observed in C3H6. Propene and cyclopropane are the resulting isomers, as illustrated below.
- It is popularly known as cis-trans isomerism.
- These isomers have different spatial arrangements of atoms in three-dimensional space.
- An illustration describing the geometric isomerism observed in the acyclic But-2-ene molecule is provided below.
- Compounds that exhibit optical isomerism feature similar bonds but different spatial arrangements of atoms forming non-superimposable mirror images.
- These optical isomers are also known as enantiomers.
- Enantiomers differ from each other in their optical activities.
- Dextro enantiomers rotate the plane of polarized light to the right whereas laevo enantiomers rotate it to the left, as illustrated below.
- An example of chain isomerism can be observed in the compound C5H12, as illustrated below.
Chiral And Achiral Molecules
The difference between chiral and achiral molecules can be explained on the basis of the plane of symmetry. If all the attached group to the central carbon atom are different then there is no plane of symmetry. Such a molecule is known as a chiral molecule.
If all the group attached to the central carbon atom are not different then there exist plane of symmetry. Such molecules are called achiral molecules. It is clear that only molecule having chiral centre will show optical isomerism.
Relationship Between The Enantiomers
Enantiomers are a type of stereoisomers in which two molecules are a non-superimposable mirror image of each other.
In other words, one of the enantiomers is a mirror image of the other which cannot be superimposed. In other words, if a mirror looks at one isomer, it would see the other. The two isomers (the original and its mirror image) have a different spatial arrangement.
Position Isomerism
Functional Isomerism
Metamerism
This type of isomerism arises due to the presence of different alkyl chains on each side of the functional group.
Tautomerism
Ring-Chain Isomerism
Stereoisomerism
This type of isomerism arises in compounds having the same chemical formula but different orientations of the atoms belonging to the molecule in three-dimensional space. The compounds that exhibit stereoisomerism are often referred to as stereoisomers. This phenomenon can be further categorized into two subtypes. Both these subtypes are briefly described in this subsection.
Ooh wow These blog are too good for board students and i will definately share it with my known person
ReplyDeleteThnk you 😊
DeleteBest blog
ReplyDeleteThnk you so much
DeleteThis is such an amazing blog. I will share it with my fellow mates. I hope all these information would be helpful for them.
ReplyDeleteHappy Teacher's Day 🙂 & keep going..
Thnk you and same to u
DeleteFabulous👌👌👌
ReplyDeleteThnxx
DeleteGreat
ReplyDeleteThnk you
DeleteNice...
ReplyDeleteThnk u
DeleteThis comment has been removed by the author.
ReplyDeletenice ...👍👍👍👍👍
ReplyDeleteThnk u
DeleteHi sir / mam
ReplyDeleteMy name is Priya I am in 10th standard mene apka last post dekha tha carbon Wala . Wo half tha so full post kar dijiye ye isomerism alag kar diya
Hlo Priya how are u
DeleteSee Priya isomerism BHI carbon Ka ek sub topic h Jo ki graduation tk use hota hai so humne ye dala hai btw ap tension Mt lo next blog Jo h wo usme hum carbon ko Pura cover denge
Okay I am waiting
DeleteHello i am in 10th class of DAV school Maharastra meri friend ne share kiya tha link ap sample paper bi provide karte ho kiya ?
ReplyDeleteHello student welcome to our blog. Abhi to hum important topics ko discuss kr rhe h bt jaldi hi hamari app launch home wali hai wha apko study se related San kch milega
DeleteKabh ayega apka app kaha se milega
DeleteBhot jld aayega jb b aayega hm apko pakka inform krnege. bs aap esi support Krte rho hme 😊
Deleteeste é um blog legal e eu também visitei seus outros blogs. Você está fazendo um ótimo trabalho, autor
ReplyDeleteThank you for your lovely comment and keep supporting us 🙂
DeletePrediction tutorial great work i always appreciate your work the way of explaining iss to good simple and effective notes
ReplyDeleteHello I just want to know you are handling your page alone or in a team
ReplyDeleteHello actually I m doing along with my partner
DeleteAnd we are small team .
And thank u for comment and pls keep supporting to us 😊
This comment has been removed by the author.
DeleteOkay great would you like to join with us ?
DeleteSrry currently we are doing alone if in future we do so then we will contact you .and btw Thnxx for your concern 😊
DeleteHi sugandha this side happy to see you again 👍👍
ReplyDeleteHlo mam Thnxx for your lovely comment and keep support us 😀
DeleteGood work
ReplyDelete